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Учебное пособие 1908

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2. The outlet temperature of

2. on lump coal.

 

 

 

 

the synthesis gas is generally

 

 

 

 

 

 

 

low ...

 

 

 

 

 

 

 

 

 

 

 

3. Moving-bed processes

3. tend to become entrained in

operate ...

 

 

the syngas and leave the bed

 

 

 

overhead.

 

 

 

 

 

4. An excessive amount of

4. they are more suited for

fines, particularly if the coal

gasifying

reactive

feedstocks,

has

strong

caking

such as low-rank coals and

properties,...

 

biomass.

 

 

 

 

 

5. Fluid-bed gasifiers offer ...

5.

temperatures

below

the

 

 

 

softening point of the ash,

 

 

 

since ash slagging will disturb

 

 

 

the fluidization of the bed.

 

6. The operation of fluid-bed

6. a bed in which the coal

gasifiers is generally restricted

moves

slowly

downward

to ...

 

 

under gravity as it is gasified,

 

 

 

generally by a counter-current

 

 

 

blast.

 

 

 

 

 

7. Sizing of the particles in the

7.

extremely

good

mixing

feed is critical; material that is

between

feed

and

oxidant,

too fine will ...

 

which promotes both heat and

 

 

 

mass transfer.

 

 

 

 

8. The

lower

temperature

8. even if high slagging

operation

of

fluid-bed

temperatures are

reached

in

processes means that ...

the heart of the bed.

 

 

Упражнение 8. Переведите текст, пользуясь словарем.

Entrained-flow gasifiers operate with feed and blast in cocurrent flow. The residence time in these processes is short (a few seconds). The feed is ground to a size of 100 µm or less to promote mass transfer and allow transport in the gas. Given the short residence time, high temperatures are required to ensure a good conversion, and therefore all entrained-flow gasifiers operate

31

in the slagging range. The high temperature operation creates a high oxygen demand for this type of process. Entrained-flow gasifiers do not have any specific technical limitations on the type of coal used, although coals with a high moisture or ash content will drive the oxygen consumption to levels where alternative processes may have an economic advantage.

There are one or two processes that do not fit into any of these three main categories. This includes in situ gasification of coal in the underground seam as well as molten bath processes.

One important point to note is the significance of the slagging behavior of the ash. At temperatures above the ash softening point, the ash becomes sticky and will agglomerate, causing blockage of beds or fouling of heat-exchange equipment. Once above the slagging temperature, at which point the ash has a fully liquid behaviour with a low viscosity, it is possible again to remove it from the system reliably. Thus, for all processes, there is a feedstock-specific "no-go" temperature range between the softening and slagging temperatures of the ash.

Упражнение 9. Переведите следующие предложения на английский язык и запишите их.

1.Газогенератор с подвижным слоем характеризуется пластом, в котором уголь медленно опускается под действием силы тяжести в процессе образования газа.

2.Температура на выходе синтезируемого газа обычно низкая, даже если в середине пласта достигаются высокие температуры ошлакования.

3.Процессы в подвижном слое происходят только в крупнокусковом угле.

4.Избыточное количество угольной мелочи, особенно, если уголь обладает свойством сильной спекаемости, может блокировать прохождение поднимающегося вверх синтетического газа.

5.Газогенератор с псевдоожиженным слоем обеспечивает очень хорошее смешивание сырья и окислителя, что

32

ускоряет тепло и массообмен.

6. Работа газогенераторов с псевдоожиженным слоем обычно ограничена температурами ниже точки размягчения золы, поскольку ошлакование золы будет нарушать псевдоожижение пласта.

7.Сортировка частиц в сырье важна, поскольку слишком мелкодисперсный материал стремится к вовлечению

всинтетический газ и покидает верхний погон пласта.

8.Низкая рабочая температура процессов с псевдоожиженным слоем означает, что они более пригодны для превращения в газ химически активного сырья, такого как низкокачественный уголь и биомасса.

Упражнение 10. Составьте аннотацию текста «Gasification Processes», используя в качестве плана ответы на вопросы упражнения 5.

Упражнение 11. Выпишите из правой колонки русские слова и словосочетания, соответствующие английским из левой колонки.

1. gasification processes

1.

температура ошлакования

2. moving-bed gasifier

2.

синтезированный газ

3. fluid-bed gasifier

3.

тепло и массообмен

4. entrained-flow gasifier

4.

газогенератор с

5. a bed

фиксированным слоем

6. coal

5.

зола, пепел, шлак

7. counter-current blast

6.

спекаемость

8. pyrolisis products

7.

точка размягчения

9. synthesis gas

8.

температура на выходе

10. slagging temperature

9.

низкосортный уголь

11. lump coal

10. процессы газификации

12. outlet temperature

11. время удержания

13. fines

12. ванна с расплавленным

14. caking property

металлом

15. feed

13. ошлакование

33

16. oxidant

14.

засорение

17. heat and mass transfer

теплообменного

18. fuel

оборудования

19. ash

15.

подземный пласт

20. carbon conversion

16.газогенератор с

21. softening point

газификацией в потоке

22. fluidization of the bed

17.

газификация химически

23. slagging

активного сырья

24.gasifying reactive

18.

низкая вязкость

feedstocks

19.

уголь

25. low-rank coal

20.

клейкий, липкий

26. residence time

21.

измельчать

27. to grind (ground)

22.газогенератор с

28. underground seam

подвижным слоем

29. molten bath

23.

псевдоожижение пласта

30. sticky

24.

продукты пиролиза

31. fouling of heat-exchange

25.

угольная мелочь

equipment

26.

противоточный взрыв

32. low viscosity

27.

окислитель

33. fixed-bed gasifier

28.

сырье

 

29.газогенератор с

 

псевдоожиженным слоем

 

30.

топливо

 

31.

пласт

 

32.

крупнокусковой уголь

 

33.

химическое

 

превращение углерода

UNIT 4

Упражнение 1. Прочтите слова и словосочетания и постарайтесь запомнить их русские эквиваленты.

air separation plant –

methanol – метанол

воздухоразделительная

moving-bed processes

установка, установка для

(технологические) процессы

34

разделения воздуха ammonia – аммиак

bed – слой породы, пласт carbon monoxide – угарный газ coke – кокс

to draw – отбирать, извлекать endothermic reaction

эндотермическая реакция

to feed – подавать, подводить feedstock – сырье для промышленности

furnace – печь, топка, котел high-gradeвысокосортный; высококачественный; богатый (о руде)

heating value – теплота сгорания (топлива), теплопроводность hydrogen – водород

1ow-rank – низкокачественный

сподвижным слоем nitrogen – азот producer gas process –

(технологические) процессы

сгенераторным газом product gas – получаемый газ

red-hotраскаленный докрасна, краснокалильный rotating grate

вращающаяся колосниковая решетка

steam – пар

synthesis gas синтез-газ tar – смола

water gas – водяной

(голубой) газ water gas process –

конверсия водяного газа

Упражнение 2. Переведите слова на русский язык, обращая внимание на суффиксы.

Historical – historically, atmosphere – atmospheric, slow – slowly, to react – reactor, present – presence, local – locally, industry – industrial, particular – particularly, to locate – location, to differ – different, to purify – purification, to separate – separation.

Упражнение 3. Прочтите и переведите интернациональные слова:

Role, reactor, product, to transport, distance, industrial, energy, form, temperature, to stop, synthesis, optimum, endothermic, reaction, cycle, chemical.

35

Упражнение 4. Переведите предложения на русский язык, используя терминологию упражнения 1.

1.Moving-bed processes аrе the oldest processes, and two in particular, the producer gas process and the water gas process, played аn important role in the early production of synthesis gas from coal and coke.

2.When using 1ow-rank feedstocks such as wood, the heating value of the gas саn bе as low as 3500 kJ/m3.

3.Gas producers continue to bе built in small numbers today where gas is required locally for firing industrial furnaces, particularly in locations where coal is the оnlу available energy form.

4.The water gas process is а discontinuous process in which steam reacts with red-hot coke to form hydrogen and carbon monoxide.

5.The reason for the two different directions of steam flow was to make optimum use of the heat in the bed, which is required do drive the endothermic water gas reaction.

6.Before the advent of large-scale air separation plants, the water gas process was the only means for making high-grade synthesis gas for chemical purposes.

Прочтите и переведите текст, а затем выполните следующие за ним упражнения.

MOVING-BED PROCESSES

Historically, moving-bed processes аrе the oldest processes, and two in particular, the producer gas process and the water gas process, played аn important role in the early production of synthesis gas from coal and coke. The preferred feedstocks were in general coke or anthracite, as otherwise the gas needs extensive cleaning to remove tars from the gas. Both processes operate at atmospheric pressure.

In the producer gas process, humidified air is blown upward

36

through а deep bed of coal or coke. The coal is fed from the top and moves slowly downwards as it is consumed. Ash is drawn off at the bottom of the reactor from а rotating grate. The air reacts with the соаl, thereby producing а gas with а lower heating value of 6500 kJ/m3. The рresence of about 50% nitrogen in the product gas is the main cause for this low value. The advantage of the process was that it was continuous. The main drawback is that because of its low heating value, producer gas cannot be transported over 1ong distances. When using low-rank feedstocks such as wood, the heating value of the gas саn bе as low as 3500 kJ/m3. Gas producers continue to bе built in small numbers today where gas is required locally for firing industrial furnaces, particularly in locations where coal is the оnlу available energy form.

The water gas process is а discontinuous process in which steam reacts with red-hot coke to form hydrogen and carbon monoxide. First, the coal or coke bed is heated bу blowing air upward through the bed to temperatures of about 1300ºC. Then the air flow is stopped and steam is passed through the соаl or coke bed, first upward and then downward, thereby producing synthesis gas. The reason for the two different directions of steam flow was to make optimum use of the heat in the bed, which is required do drive the endothermic water gas reaction. When the temperature has dropped to about 900ºС, the steam “run” is stopped and the cycle is repeated. After purification the syngas саn bе used for the synthesis of ammonia or methanol. Before the advent of large-scale air separation plants, the water gas process was the only means for making high-grade synthesis gas for chemical purposes. In order to obtain а continuous gas flow, at least three water gas reactors аrе required.

Упражнение 5. Найдите в тексте данные ниже слова и словосочетания и напишите их русские эквиваленты.

Extensive cleaning, to remove tars, atmospheric pressure, upward, downward, а deep bed of coal, to move slowly

37

downwards, bottom of the reactor, product gas, low value, continuous, low heating value, producer gas, low-rank feedstocks, industrial furnaces, discontinuous, red-hot coke, steam flow, largescale air separation plants, chemical purposes.

Упражнение 6. Найдите в тексте ответы на следующие вопросы:

1.What processes played an important role in the production of synthesis gas from coal and coke?

2.What condition do both processes operate under?

3.What occurs in the producer gas process?

4.What is the main cause for the low heating value?

5.What is the advantage of the producer gas process?

6.What is the main drawback of the process?

7.Where are gas producers built?

8.What kind of process is the water gas process?

9.How does the water gas process occur?

10.What was the reason for the two different directions of steam flow?

11.When is the cycle repeated?

12.What can the syngas be used for?

Упражнение 7. Заполните пропуски предлогами и переведите предложения на русский язык.

1. ... the producer gas process, humidified air is blown upward ... а deep bed ... coal or coke.

2. Ash is drawn off ... the bottom ... the reactor ... а rotating

grate.

3.The presence ... about 50% nitrogen ... the product gas is the main cause ... this low value.

4.The water gas process is а discontinuous process ... which steam reacts ... red-hot coke to form hydrogen and carbon monoxide.

5.First, the coal or coke bed is heated … blowing air upward

38

... the bed to temperatures ... about 1300ºC.

6. ... purification the syngas саn bе used ... the synthesis ...

ammonia or methanol.

7. ... the advent ... large-scale air separation plants, the water gas process was the only means ... making high-grade synthesis gas

... chemical purposes.

Упражнение 8. Выпишите из правой колонки русские слова и словосочетания, соответствующие английским из левой колонки.

1. moving-bed process

1.

водород

2. producer gas process

2.

низкокачественный

3. water gas process

3.

эндотермическая реакция

4. synthesis gas

4.

смола

5. coke

5.

пар

6. coal

6.

зола, пепел, шлак

7. feedstock

7.

воздухоразделительная

8. anthracite

установка

9. tar

8.

синтез-газ

10. atmospheric pressure

9.

вращающаяся колосниковая

11. humidified air

решетка

12. bed

10.

кокс

13. ash

11.

метанол

14. heating value

12.

сырье для

15. nitrogen

промышленности

16. product gas

13.

промышленная печь

17. low-rank

14.

технологические процессы

18. industrial furnace

с подвижным слоем

19. steam

15.

теплота сгорания

20. red-hot

16.

высокосортный

21. hydrogen

17.

слой, пласт

22. carbon monoxide

18.

получаемый газ

23. endothermic reaction

19.

конверсия водяного пара

24. ammonia

20. уголь

25. methanol

21.

антрацит

39

26. air-separation plant

22. раскаленный докрасна

27. high-grade

23. технологические процессы

28. rotating grate

с генераторным газом

 

24.

влажный воздух

 

25.

азот

 

26. угарный газ

 

27.

аммиак

 

28.

атмосферное давление

Упражнение 9. Подберите из правой колонки соответствующие окончания предложений из левой колонки.

1. The producer gas process

1.

is blown upward through а

and the water gas process

 

deep bed of coal or coke.

 

played аn important role in ...

 

 

 

 

 

2. First, the coal or coke bed is

2.

the heating value of the gas

heated ...

 

 

саn bе as low as 3500 kJ/m3.

3. The air reacts with the соаl,

3.

the steam “run” is stopped

thereby ...

 

 

and the cycle is repeated.

 

4. Then the air flow is stopped

4.

steam reacts with red-hot

and steam is passed through

coke to form hydrogen and

the соаl or coke bed, ...

 

carbon monoxide.

 

 

5. In the producer gas process,

5.

bу blowing air upward

humidified air ...

 

 

through

the

bed

to

 

 

 

temperatures of about 1300ºC.

6. The reason for the two

6.

for

the synthesis

of

different directions of steam

ammonia or methanol.

 

flow was ...

 

 

 

 

 

 

 

7. Ash is drawn off at the

7.

first

upward

and

then

bottom of the reactor ...

 

downward, thereby producing

 

 

 

synthesis gas.

 

 

8. The water gas process is а

8.

producing а gas with а

discontinuous

process

in

lower heating value of 6500

which ...

 

 

kJ/m3.

 

 

 

9. After purification

the

9. to make optimum use of the

40